I see where the confusion came in, I don't think I explained myself clear enough in the initial post, what I was trying to say is I already have 2 instances of XP Pro 32 bit installed. My main one is on a partition of a 300 GB hard drive, and the other (new) install is on my recently established RAID setup, which is where I plan on Installing Vista, possibly via the Upgrade package.
Also: Does the Upgrade retail package include the 64 bit version, or would I have to buy it, then send out to Microsoft for a disc containing the 64 bit version? If that is the case then I'll probably just go OEM and be done with it.
Motherboard: XFX 680i SLI
CPU: Intel Core2 Duo E6550
CPU Cooler: Zalman 9500
Video Card: 2x EVGA nVidia 8800 GT
RAM: 2x 2 GB OCZ DDR2 800 (PC2 6400)
Power Supply: Seasonic S12 650 Watts